Mercury

Mercury

Mercury is a chemical element with the symbol Hg and atomic number 80. It is commonly known as quicksilver and was formerly named hydrargyrum (from Greek "hydr-" water and "argyros" silver). A heavy, silvery d-block element, mercury is the only metal that is liquid at standard conditions for temperature and pressure; the only other element that is liquid under these conditions is bromine, though metals such as caesium, gallium, and rubidium melt just above room temperature. With a freezing point of −38.83 °C and boiling point of 356.73 °C, mercury has one of the narrowest ranges of its liquid state of any metal.

Mercury occurs in deposits throughout the world mostly as cinnabar (mercuric sulfide). The red pigment vermilion, a pure form of mercuric sulfide, is mostly obtained by reaction of mercury (produced by reduction from cinnabar) with sulfur. Cinnabar is highly toxic by ingestion or inhalation of the dust. Mercury poisoning can also result from exposure to water-soluble forms of mercury (such as mercuric chloride or methylmercury), inhalation of mercury vapor, or eating seafood contaminated with mercury.

Mercury is used in thermometers, barometers, manometers, sphygmomanometers, float valves, mercury switches, and other devices though concerns about the element's toxicity have led to mercury thermometers and sphygmomanometers being largely phased out in clinical environments in favor of alcohol-filled, galinstan-filled, digital, or thermistor-based instruments. It remains in use in scientific research applications and in amalgam material for dental restoration. It is used in lighting: electricity passed through mercury vapor in a fluorescent lamp produces short-wave ultraviolet light which then causes the phosphor in the tube to fluoresce, making visible light.

Occurrence


Mercury is an extremely rare element in the Earth's crust, having an average crustal abundance by mass of only 0.08 parts per million (ppm). However, because it does not blend geochemically with those elements that constitute the majority of the crustal mass, mercury ores can be extraordinarily concentrated considering the element's abundance in ordinary rock. The richest mercury ores contain up to 2.5% mercury by mass, and even the leanest concentrated deposits are at least 0.1% mercury (12,000 times average crustal abundance). It is found either as a native metal (rare) or in cinnabar, corderoite, livingstonite and other minerals, with cinnabar (HgS) being the most common ore. Mercury ores usually occur in very young orogenic belts where rock of high density are forced to the crust of the Earth, often in hot springs or other volcanic regions.

Beginning in 1558, with the invention of the patio process to extract silver from ore using mercury, mercury became an essential resource in the economy of Spain and its American colonies. Mercury was used to extract silver from the lucrative mines in New Spain and Peru. Initially, the Spanish Crown's mines in Almaden in Southern Spain supplied all the mercury for the colonies. Mercury deposits were discovered in the New World, and more than 100,000 tons of mercury were mined from the region of Huancavelica, Peru, over the course of three centuries following the discovery of deposits there in 1563. The patio process and later pan amalgamation process continued to create great demand for mercury to treat silver ores until the late 19th century.


Former mines in Italy, the United States and Mexico which once produced a large proportion of the world supply have now been completely mined out or, in the case of Slovenia (Idrija) and Spain (Almadén), shut down due to the fall of the price of mercury. Nevada's McDermitt Mine, the last mercury mine in the United States, closed in 1992. The price of mercury has been highly volatile over the years and in 2006 was $650 per 76-pound (34.46 kg) flask.

Mercury is extracted by heating cinnabar in a current of air and condensing the vapor. The equation for this extraction is

HgS + O2 → Hg + SO2

In 2005, China was the top producer of mercury with almost two-thirds global share followed by Kyrgyzstan. Several other countries are believed to have unrecorded production of mercury from copper electrowinning processes and by recovery from effluents.
Because of the high toxicity of mercury, both the mining of cinnabar and refining for mercury are hazardous and historic causes of mercury poisoning. In China, prison labor was used by a private mining company as recently as the 1950s to create new cinnabar mercury mines. Thousands of prisoners were used by the Luo Xi mining company to establish new tunnels. In addition, worker health in functioning mines is at high risk.

The European Union directive calling for compact fluorescent bulbs to be made mandatory by 2012 has encouraged China to re-open deadly cinnabar mines to obtain the mercury required for CFL bulb manufacture. As a result, environmental dangers have been a concern, particularly in the southern cities of Foshan and Guangzhou, and in the Guizhou province in the south west.

Abandoned mercury mine processing sites often contain very hazardous waste piles of roasted cinnabar calcines. Water run-off from such sites is a recognized source of ecological damage. Former mercury mines may be suited for constructive re-use. For example, in 1976 Santa Clara County, California purchased the historic Almaden Quicksilver Mine and created a county park on the site, after conducting extensive safety and environmental analysis of the property.

Symbol		Hg
Atomic Number		80
Atomic Weight		200.59
Oxidation States		+1,+2
Electronegativity, Pauling		1.8
State at RT		liquid
Melting Point, K		234.28
Boiling Point, K		629.73

Appearance and Characteristics

Harmful effects:

Mercury and most of its compounds are highly toxic.

The pure metal is absorbed easily by inhalation, ingestion or through the skin.

It is also a chronic pollutant and mercury concentrates in animal/fish tissues in increasing amounts up the food chain.

Characteristics:

• Mercury is a dense, silvery-white, poisonous metal with a mirror-like appearance.
• It is the only common metal that is liquid at room temperature. Mercury evaporates slowly at room temperature.
• Others metals that are liquid near room temperature are gallium, francium and cesium.
• The metal is relatively stable in dry air, but in moist air tarnishes slowly to form a gray oxide coating.
• Mercury has high surface tension and, when spilled, breaks up into tiny beads.
• Mercury readily forms alloys (called amalgams) with other metals, such as silver, gold and tin. As it does not amalgamate with iron, mercury is often stored in iron containers.

Uses of Mercury

• Mercury is used in barometers and manometers (instruments for measuring the pressure of gases and liquids), because of its high density.
• The metal also has a high rate of nearly linear thermal expansion, so it is used extensively in thermometers.
• Its ease in amalgamating with metals is made use of in extracting gold, silver, and platinum from their ores.
• Mercury is widely used in making advertising signs, mercury switches and other electrical apparatus.
• It is also used in mercury-vapor lamps (which emit light rich in ultraviolet radiation). These lamps are typically used for street lighting, as sun lamps, and as UV lights (black lights).
• Various compounds of mercury are used in medicine, dentistry, cosmetics (mascara) and also in agriculture to make fungicides.